Monday, August 8, 2011

What are rare earth metals?

"Rare earth" metals aren't as rare as they sound — in fact, you're probably using some right now. They're key to a variety of everyday devices, from tablet computers and TVs to hybrid cars and wind turbines, so it may be encouraging to know several kinds are actually common. Cerium, for example, is the 25th most abundant element on Earth.

So why are they called "rare" earths? The name alludes to their elusive nature, since the 17 elements rarely exist in pure form. Instead, they mix diffusely with other minerals underground, making them costly to extract.

And, unfortunately, that isn't their only drawback. Mining and refining rare earths makes an environmental mess, leading most countries to neglect their own reserves, even as demand soars. China has been the main exception since the early 1990s, dominating global trade with its willingness to intensively mine rare earths — and to deal with their acidic, radioactive byproducts. That's why the U.S., despite large deposits of its own, still gets 92 percent of its rare earths from China.

This wasn't a problem until recently, when China began tightening its grip on rare earths. The country first imposed trade limits in 1999, and its exports shrank by 20 percent from 2005 to 2009. They then took a dramatic nosedive in 2010, squeezing global supplies amid a dispute with Japan, and they've fallen even further in 2011. China says it's being stingy for environmental reasons, not economic leverage, but the cutbacks have nonetheless caused major price spikes. The price of neodymium hit $129 per pound in May, for example, up from just $19 a year earlier.

Many of China's customers are already shopping around: Deposits in Russia, Brazil, Australia and South Asia have drawn widespread interest, as has the only rare earths mine in the U.S. But even though that mine reopened in April after a decade-long hiatus — and holds the largest rare earth deposit outside China — the U.S., like many countries, doesn't want to be the world's new go-to source for rare earths. "Diversified global supply chains are essential," the Energy Department said in a 2010 report.



Why are so many countries reluctant to exploit their own rare earth reserves? And what makes rare earths so unique to begin with? For answers to these and other questions, check out the following overview of these 17 mysterious metals.

A rare breed

Much of rare earths' appeal lies in their ability to perform obscure, highly specific tasks. Europium provides red phosphor for TVs and computer monitors, for example, and it has no known substitute. Cerium similarly rules the glass-polishing industry, with "virtually all polished glass products" dependent on it, according to the U.S. Geological Survey.

Permanent magnets are another big role for rare earths. Their light weight and high magnetic strength have made it possible to miniaturize a wide range of electronic parts, including many used in home appliances, audio/video equipment, computers, cars and military gear. Innovations like small, multi-gigabyte jump drives and DVD drives likely wouldn't exist without rare earth magnets, which are often made from a neodymium alloy but may also contain praseodymium, samarium, gadolinium or dysprosium.

While producing rare earths can cause environmental problems, they have an eco-friendly side, too. They're vital to catalytic converters, hybrid cars and wind turbines, for example, as well as energy-efficient fluorescent lamps and magnetic-refrigeration systems. Their low toxicity is an advantage, too, with lanthanum-nickel-hydride batteries slowly replacing older kinds that use cadmium or lead. Red pigments from lanthanum or cerium are also phasing out dyes that contain various toxins. (For more information, see the list below of rare earth metals and their uses.)

Look whose toxin

Lots of green technologies rely on rare earths, but ironically, rare earth producers have a long history of harming the environment to get the metals. Like many industries that process mineral ores, they end up with toxic byproducts known as "tailings," which can be contaminated with radioactive uranium and thorium. In China, these tailings are often dumped into "rare earth lakes" like the ones pictured below:

As the AFP reports, farmers near China's Baotou mine complain of dying crops, lost teeth and lost hair, while soil and water tests show high levels of carcinogens in the area. China has only recently begun cracking down on such pollution, perhaps learning a lesson from Mountain Pass, Calif., which supplied most of the world's rare earths until economic and environmental pressures forced it to close in 2002. The mine's profits had declined for years as China slashed rare earth prices with its own mining frenzy, while a series of waste water leaks from 1984 to 1998 spilled thousands of gallons of toxic sludge into the California desert, sullying the mine's public image.

But as China's output now declines, rising prices have once again opened the door for Mountain Pass. In April, Molycorp Minerals hosted an event heralding the return of its idle mine, which some politicians say is key to reducing U.S. reliance on imports. "We must wean ourselves off our total dependence on China for rare earths," Rep. Mike Coffman, R-Colo., recently told the Financial Times. It's hard to disagree, given rare earths' global importance, but the specter of spills still lingers. Molycorp knows that, CEO Mark Smith told the Atlantic in 2009, and aims to be "environmentally superior, not just compliant." The company is spending $2.4 million a year on monitoring and compliance, which raises costs, but Smith says that won't deter anxious buyers. "We're being contacted by Fortune 100 companies who are worried about where they're going to get their next pound of [rare earths]," he told Bloomberg News in January. "What they want to talk to us about is long-term, stable, secure supplies."

Molycorp is allowed to deepen its pit at Mountain Pass (pictured) by an extra 300 feet over the next 30 years, which could boost global supplies of rare earths by 10 percent a year. And it's not the only company itching to tap U.S. reserves: Wings Enterprises is reviving its Pea Ridge mine in Missouri, for instance, while a new mine in Wyoming may open as early as 2014. Overall, experts say the growth of rare earth mining is all but inevitable, adding a toxic asterisk to many technologies designed to fight climate change.

But there may be one way to reduce demand for new mining: rare earth recycling. China's export policies have led some Japanese companies to recycle rare earths, such as Mitsubishi, which is studying the cost of reusing neodymium and dysposium from washing machines and air conditioners. Hitachi, which uses up to 600 tons of rare earths each year, expects recycling to fill 10 percent of its needs by 2013. The U.N. also recently launched a project to track discarded "e-waste" like cellphones and TVs, hoping to boost recycling not only of rare earths but also gold, silver and copper. Yet until such programs are more cost-effective, the U.S. and other countries will almost certainly keep testing just how rare — and how safe — rare earths really are.



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